Franklin International
MATERIAL SAFETY DATA SHEET
MSDS Name: Titebond Polyurethane Glue
MSDS Number: 2300
Revision Date: 6/14/04
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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Titebond Polyurethane Glue
CAS Number: none
HMIS Hazard Rating: Health: 2 Fire: 1 Reactivity: 0
Company Identification: Franklin International
2020 Bruck Street
Columbus OH 43207
Contact: Franklin Technical Services
Telephone/Fax: (800) 877-4583 (614) 445-1493
Emergency Phone (24 Hour): Franklin Security
(614) 445-1300
Chemtrec (24 Hour): (800) 424-9300
Chemtrec International: (703) 527-3887
Product Class urethane
Product Use: adhesive
Product Code: 3810
Division: Construction Adhesives & Sealants
SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients CAS Number Percent
4,4'-diphenylmethane diisocyanate 101-68-8 20.70
OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable.
SECTION 3 - HAZARD IDENTIFICATION
NOTE:
This product reacts with water, releasing carbon dioxide.
EMERGENCY OVERVIEW:
WARNING: EYE AND SKIN IRRITANT. POTENTIAL SKIN AND RESPIRATORY
SENSITIZER. Contains isocyanate containing polymers. KEEP OUT OF REACH
OF CHILDREN. In the case of a spill: evacuate and ventilate the spill
area, wear full protective equipment including respiratory equipment
during clean-up.
ROUTES OF ENTRY:
Ingestion: Yes
Inhalation: Yes
Skin: Yes
Eye: Yes
INHALATION:
At room temperature, vapors are minimal due to low vapor pressure. In
some individuals an allergic reaction may occur. May cause respiratory
sensitization in susceptible individuals. MDI concentrations below
exposure guidelines may cause allergic reactions in individuals
already sensitized. Symptoms may include coughing, difficult breathing
and a feeling of tightness in the chest. Effects may be delayed.
Impaired lung function (decreased ventilation capacity) has been
associated with overexposure to isocyanates.
INGESTION:
No hazard expected in normal industrial use. Ingestion is not a likely
route of exposure.
SKIN:
Prolonged or repeated exposure may cause skin irritation. Skin contact
may result in allergic skin reactions or respiratory sensitization but
is not expected to result in absorption of amounts sufficient to cause
other adverse effects. Material may stick to skin causing irritation
upon removal. May stain skin.
EYE:
May cause slight eye irritation. Corneal injury is unlikely.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Respiratory conditions such as asthma.
CARCINOGENICITY:
IARC: No
NTP: No
OSHA: No
ACGIH: No
REPRODUCTIVE TOXICITY:
In laborotory animals, MDI/polymeric MDI do not produce birth defects;
other fetal effects occurred only at doses which were toxic to the
mother.
TARGET ORGANS:
Eyes, skin, and respiratory tract.
SECTION 4 - FIRST AID MEASURES
INHALATION:
Remove to fresh air. If not breathing give mouth to mouth
resuscitation. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport to
a medical facility.
INGESTION:
If swallowed, seek medical attention. Do not induce vomiting unless
directed to do so by medical personnel.
SKIN:
Wash off with flowing water or shower. Contact physician if persistent
irritation occurs.
EYE:
Irrigate with flowing water immediately and continuously for 15
minutes. Consult medical personnel. Material containing MDI may react
with moisture of the eye forming thick material which may be difficult
to wash from the eye.
SECTION 5 - FIRE-FIGHTING MEASURES
Flammability Class (OSHA) IIIB
Flash Point: > 200F
Setaflash
Explosive Range: Not Applicable
EXTINGUISHING MEDIA:
Carbon dioxide, dry chemical, or foam. For large scale fires, alcohol
resistant foams are preferred if available. Water may be used as a
blanket for fire extinguishment. If water is used,it should be used in
a very large quantity. The reaction between water and isocyanate may
be vigorous. If possible, contain fire run off water.
HAZARDOUS COMBUSTION PRODUCTS:
When burning, product will release carbon monoxide, carbon dioxide,
nitrogen oxide fumes, and isocyanate vapors.
FIRE FIGHTING PROCEDURES:
Fire fighters should use positive pressure self-contained breathing
appartus and full protective clothing. Down-wind personnel must be
evacuated.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
CONTAINMENT TECHNIQUES:
Use inert absorbent to dike the spill. Keep away from drains.
CLEAN-UP:
Major spill: Evacuate and ventilate spill area, wear full protective
equipment including respiratory equipment during clean up. If
temporary control of isocyanate vapor is required, a blanket of
protein foam may be place over the spill. Large quantities may be
pumped into a closed but not sealed containers for disposal. Do not
make pressure tight. Transport to a well-ventilated area (outside) and
treat with neutralizing solution consisting of a mixture of water and
3-8% concentrated ammonium hydroxide or 5-10% sodium carbonate. Add
about 10 parts of neutralizer per part of isocyanate with mixing.
Allow to stand for 48 hours letting evolved carbon dioxide to escape.
Decontaminate floor using water/ammonia solution with 1-2% detergent
letting stand over effected area for at least 10 minutes. Cover mops
and brooms used for this with plastic and dispose of properly (often
by incineration).
EMERGENCY MEASURES:
Isolate hazard area. Keep unnecessary and unprotected personnel from
entering area. Wear all appropriate personal protection equipment
(PPE) (see Section 8).
SECTION 7 - HANDLING AND STORAGE
HANDLING:
In accordance with good manufacturing practices, good ventilation of
the processing area is recommended. Gloves are recommended as product
is difficult to remove from effected areas if contact with skin
occurs.
STORAGE:
Store in tightly closed containers to protect from atmospheric
moisture. Replace outage with inert nitrogen. Store at temperature of
75F to 105F.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
4,4'-diphenylmethane diisocyanate
N/est N/est N/est N/est N/est
The ACGIH TLV for 4,4'-diphenylmethane diisocyanate is .005 ppm. The
OSHA Ceiling for 4,4'-diphenylmethane diisocyanate is .02 ppm.
ENGINEERING CONTROLS:
Use local exhaust as needed to maintain occupational exposure limits.
RESPIRATORY PROTECTION:
Atmospheric levels should be maintained below the exposure guidelines.
For emergency and other conditions where an exposure guidelines may be
exceeded, use an approved positive-pressure self contained breathing
apparatus or supplied air respirator with an auxiliary self-contained
air supply.
EYE PROTECTION:
Chemical splash goggles (ANSI Z87.1 or approved equivalent).
SKIN PROTECTION:
Use impervious materials made of butyl or nitrile rubber where skin
contact may occur.
GENERAL:
Safety shower and eye wash station.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form: LIQUID
Appearance/Color: BROWN
Odor: MILD
Solubility (in water): NIL
pH Value: Not Applicable
Boiling Range/Point: NOT APPLICABLE
Evaporation Rate: NOT APPLICABLE
% Volatile: Not Applicable
Specific Gravity: 1.15
VOC: NOT APPLICABLE
SECTION 10 - STABILITY AND REACTIVITY
Stability: This product is stable
Hazardous Polymerization: Hazardous polymerization will not occur
CONDITIONS TO AVOID:
Avoid prolonged heating over 160F (71C) or storage below 75F (24C).
Stable when stored under normal conditions. Decomposition begins at
350F (177C).
INCOMPATIBLITY:
Water, acids, bases, alcohols, metal compounds, and surface active
materials. Avoid water as it reacts to generate heat, CO2, and
insoluble urea. Some reactions may be vigorous.
HAZARDOUS DECOMPOSITION PRODUCTS:
Excessive heating can produce isocyanate vapor, mist and other
hazardous organic compounds.
Decomposition may occur with incompatible reactants, especially
strong bases, water or temperatures over 320F (160C).
SECTION 11 - TOXICOLOGICAL INFORMATION
Acute and chronic health effects are not expected as long as good
industrial hygeine and safety precautions are followed.
SECTION 12 - ECOLOGICAL INFORMATION
This formulation has not been tested for environmental effects.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Disposal of this product must comply with all applicable federal,
state and local regulations.
CONTAINER DISPOSAL:
Disposal of this container should comply with all applicable federal,
state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
UN Number NONE
UN Pack Group N/A
UN Class NONHAZ
ICAO/IATA Class NON HAZARDOUS
IMDG Class NON HAZARDOUS
Shipping Name NON HAZARDOUS
Packaging may not be approved for shipping by air. Please contact
Franklin International for further information.
SECTION 15 - REGULATORY INFORMATION
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and of 40 CFR 372:
Chemical Name CAS Number Percent
4,4'-diphenylmethane diisocyanate 101-68-8 20.70
TSCA (Toxic Substances Control Act Inventory):
All components of this product are listed on the TSCA inventory except
as exempted.
PENNSYLVANIA:
Hazardous component required to be listed at 1% or greater:
4,4'-diphenylmethane diisocyanate 101-68-8
Non-hazardous components required to be listed at 3% or greater:
reacted urethane prepolymer, mixture
NEW JERSEY:
reacted urethane prepolymer, mixture
4,4'-diphenylmethane diisocyanate, 101-68-8
SECTION 16 - OTHER INFORMATION
DISCLAIMER:
While the information and recommendations set forth herein are
believed to be accurate as of the data hereof, Franklin International
makes no warranty, express or implied, with respect thereto and
disclaims all liability from reliance thereon.