Franklin International
MATERIAL SAFETY DATA SHEET
MSDS Name: Titebond Liquid Hide Glue
MSDS Number: 5013
Revision Date: 6/17/04
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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Titebond Liquid Hide Glue
CAS Number: none
HMIS Hazard Rating: Health: 1 Fire: 1 Reactivity: 0
Company Identification: Franklin International
2020 Bruck Street
Columbus OH 43207
Contact: Franklin Technical Services
Telephone/Fax: (800) 877-4583 (614) 445-1493
Emergency Phone (24 Hour): Franklin Security
(614) 445-1300
Chemtrec (24 Hour): (800) 424-9300
Chemtrec International: (703) 527-3887
Product Class Protein dispersion
Product Use: wood glue
Product Code: 1103
Division: Construction Adhesives & Sealants
SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients CAS Number Percent
ammonium thiocyanate 1762-95-4 8.30
dicyandiamide 461-58-5 3.70
OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable.
SECTION 3 - HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
An amber colored liquid with little odor. Slippery in the wet state.
ROUTES OF ENTRY:
Inhalation: yes
Ingestion: yes
Skin: no
Eye: yes
INHALATION:
May be irritating to upper respiratory tract.
INGESTION:
Single dose oral toxicity is considered to be extremely low. No
hazards expected from swallowing small amounts incidental to normal
handling operations. Ingestion may cause gastrointestinal irritation.
SKIN:
Prolonged or repeated skin contact can cause irritation.
EYE:
Mildly irritating to eyes.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
None expected in normal use.
CARCINOGENICITY:
IARC: No
NTP: No
OSHA: No
REPRODUCTIVE TOXICITY:
None anticipated based on product formula.
TARGET ORGANS:
Target organs: eyes, skin, and respiratory system.
SECTION 4 - FIRST AID MEASURES
INHALATION:
Remove to fresh air. If difficulty persists, seek medical attention.
INGESTION:
If swallowed, call poison control center immediately. Follow their
specific instructions. Do not induce vomiting.
SKIN:
Wash with soap and water. Contact a physician if irritation develops
or persists.
EYE:
Hold eyelids apart and flush with plenty of water for at least 15
minutes. Seek medical attention.
SECTION 5 - FIRE-FIGHTING MEASURES
Flammability Class (OSHA) IIIB
Flash Point: > 200 F
Setaflash
Explosive Range: Not applicable
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, water spray, or ABC dry chemical
when fighting fires involving this product.
HAZARDOUS COMBUSTION PRODUCTS:
Not applicable (water based product). However, solid material will
support combustion if water has evaporated.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
CONTAINMENT TECHNIQUES:
Use inert absorbent to dike the spill. Keep away from drains.
CLEAN-UP:
If possible pump liquid into an approved container or spread absorbent
over spill and shovel product/absorbent mixture into an approved
container. If product has dried scrape up and place in an approved
container.
EMERGENCY MEASURES:
None required.
SECTION 7 - HANDLING AND STORAGE
HANDLING:
Wash hands before eating.
STORAGE:
Keep from freezing. Best when stored above 40 F (4 C).
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
ammonium thiocyanate
N/est N/est N/est N/est N/est
dicyandiamide
N/est N/est N/est N/est N/est
ENGINEERING CONTROLS:
Natural ventilation should be adequate under normal conditions.
Maintain standard plant ventilation.
OTHER:
Facilities storing or utilizing any chemical should be equipped with
an eyewash facility and a safety shower.
RESPIRATORY PROTECTION:
Respiratory protection is not expected to be necessary under normal
use. Follow requirements for respiratory protection in OSHA 1910.134.
EYE PROTECTION:
Chemical splash goggles (ANSI Z87.1 or approved equivalent).
SKIN PROTECTION:
Where skin contact can occur, wear impervious gloves.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form: Liquid
Appearance/Color: Amber
Odor: Slight
Solubility (in water): Complete
pH Value: 6.5
Boiling Range/Point: 212.øF
Evaporation Rate: Slower than n-Butyl Acetate
% Volatile: 48.%
Specific Gravity: 1.15
VOC: 0
SECTION 10 - STABILITY AND REACTIVITY
Stability: This product is stable
Hazardous Polymerization: Hazardous polymerization will not occur
CONDITIONS TO AVOID:
High temperatures promote hydrolysis.
INCOMPATIBLITY:
Strong acids and strong bases
SECTION 11 - TOXICOLOGICAL INFORMATION
Acute and chronic health effects are not expected as long as good
industrial hygeine and safety precautions are followed.
SECTION 12 - ECOLOGICAL INFORMATION
This formulation has not been tested for environmental effects.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Disposal of this product must comply with all applicable federal,
state and local regulations.
CONTAINER DISPOSAL:
Disposal of this container should comply with all applicable federal,
state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
UN Number none
UN Pack Group N/A
UN Class Nonhaz
ICAO/IATA Class Nonhazardous
IMDG Class Nonhazardous
Shipping Name Nonhazardous
Packaging may not be approved for shipping by air. Please contact
Franklin International for further information.
SECTION 15 - REGULATORY INFORMATION
TSCA (Toxic Substances Control Act Inventory):
All components of this product are listed on the TSCA inventory except
as exempted.
PENNSYLVANIA:
Hazardous components required to be listed at 1% or more:
ammonium thiocyanate; thiocyanic acid, ammonium salt; 1762-95-4
Non-hazardous components required to be listed at 3% or more:
dicyandiamide 461-58-5; hide glue 9007-34-5; water 7732-18-5
NEW JERSEY:
powdered hide glue 9007-34-5; water 7732-18-5; ammonium thiocyanate
1762-95-4; dicyandiamide 461-58-5; polyalkene glycol 9038-95-3
SECTION 16 - OTHER INFORMATION
DISCLAIMER:
While the information and recommendations set forth herein are
believed to be accurate as of the data hereof, Franklin International
makes no warranty, express or implied, with respect thereto and
disclaims all liability from reliance thereon.