Franklin International
MATERIAL SAFETY DATA SHEET
MSDS Name: Titebond Solvent Free Construction Adhesive
MSDS Number: 7471
Revision Date: 6/14/04
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SECTION 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Name: Titebond Solvent Free Construction
Adhesive
CAS Number: none
HMIS Hazard Rating: Health: 1 Fire: 1 Reactivity: 0
Company Identification: Franklin International
2020 Bruck Street
Columbus OH 43207
Contact: Franklin Technical Services
Telephone/Fax: (800) 877-4583 (614) 445-1493
Emergency Phone (24 Hour): Franklin Security
(614) 445-1300
Chemtrec (24 Hour): (800) 424-9300
Chemtrec International: (703) 527-3887
Product Class Solvent Free adhesive
Product Use: construction adhesive
Product Code: 3631
Division: Construction Adhesives & Sealants
SECTION 2 - COMPOSITION AND INFORMATION ON INGREDIENTS
Hazardous Ingredients CAS Number Percent
ethylene glycol 107-21-1 1.52
OSHA PELs & ACGIH TLVs are listed in Section 8 where applicable.
SECTION 3 - HAZARD IDENTIFICATION
EMERGENCY OVERVIEW:
CAUTION: IRRITANT. Contains ethylene glycol. Beige colored mastic with
mild odor. Slippery in the wet state.
ROUTES OF ENTRY:
Inhalation: yes
Ingestion: yes
Skin: no
Eye: yes
INHALATION:
Vapors may be irritating to the eyes, nose, throat and lungs.
INGESTION:
Ingestion is not a probable route of exposure. Harmful if swallowed.
SKIN:
Prolonged or repeated skin contact can cause irritation.
EYE:
Mildly irritating to eyes.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
Preexisting skin and respiratory conditions.
CARCINOGENICITY:
IARC: No
NTP: No
OSHA: No
REPRODUCTIVE TOXICITY:
None anticipated based on product formula. Ethylene glycol may cause
birth defects based on tests with laboratory animals.
TARGET ORGANS:
Prolonged or repeated overexposure may cause eye, skin, respiratory
system, central nervous system, peripheral nervous system, liver and
kidney damage.
SECTION 4 - FIRST AID MEASURES
INHALATION:
Remove to fresh air. If difficulty persists, seek medical attention.
INGESTION:
Call poison control center immediately. Follow their specific
instructions. Do not induce vomiting.
SKIN:
Wash with soap and water. Contact a physician if irritation develops
or persists.
EYE:
Hold eyelids apart and flush with plenty of water for at least 15
minutes. Seek medical attention.
SECTION 5 - FIRE-FIGHTING MEASURES
Flammability Class (OSHA) IIIB
Flash Point: > 200.øF
Setaflash
Explosive Range: Not applicable
EXTINGUISHING MEDIA:
Use alcohol foam, carbon dioxide, water spray, or ABC dry chemical
when fighting fires involving this product.
HAZARDOUS COMBUSTION PRODUCTS:
Incomplete combustion can yield low molecular weight hydrocarbons and
carbon monoxide.
FIRE FIGHTING PROCEDURES:
Wear a NIOSH approved self contained breathing apparatus. Wear
appropriate personal protective equipment.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
CLEAN-UP:
Spread absorbent over material and scrape up material/absorbent and
place in an approved container. If product has dried scrape up and
place in an approved container.
EMERGENCY MEASURES:
None required.
SECTION 7 - HANDLING AND STORAGE
HANDLING:
Wash thoroughly after handling. Avoid prolonged or repeated contact
with skin. Do not take internally. Close container after each use.
Keep away from children.
STORAGE:
Keep away from food and drinking water.
Store in a cool, dry place.
PRECAUTIONARY STATEMENT:
Keep out of the reach of children.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Occupational Exposure Limits
ACGIH TLV ACGIH TLV-C ACGIH STEL OSHA STEL OSHA PEL
ethylene glycol
100.00 mg/M3 100.00 mg/M3 N/est N/est N/est
ENGINEERING CONTROLS:
Use local exhaust as needed to maintain occupational exposure limits.
OTHER:
Facilities storing or utilizing any chemical should be equipped with
an eyewash facility and a safety shower.
RESPIRATORY PROTECTION:
Respiratory protection is not expected to be necessary under normal
use. Follow requirements for respiratory protection in OSHA 1910.134.
EYE PROTECTION:
Chemical splash goggles (ANSI Z87.1 or approved equivalent).
SKIN PROTECTION:
Where skin contact can occur, wear impervious gloves.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Form: Mastic
Appearance/Color: Beige
Odor: Mild
Solubility (in water): Miscible
pH Value: 5.0
Boiling Range/Point: 212.øF
Evaporation Rate: Slower than n-Butyl Acetate
% Volatile: 25.%
Specific Gravity: 1.40
VOC: 6.6 g/l
SECTION 10 - STABILITY AND REACTIVITY
Stability: This product is stable
Hazardous Polymerization: Hazardous polymerization will not occur
CONDITIONS TO AVOID:
Strong acids and strong bases
INCOMPATIBLITY:
Strong oxidizing agents, acids and bases.
HAZARDOUS DECOMPOSITION PRODUCTS:
Will not occur.
SECTION 11 - TOXICOLOGICAL INFORMATION
Ethylene glycol can irritate the eyes and skin. Prolonged overexposure
via inhalation can cause pulmonary edema plus liver and kidney damage.
The central nervous system may be affected exhibiting dizziness,
weakness, nausea and headache. Brain damage has resulted in humans
from swallowing lethal or near lethal amounts of ethylene glycol.
Ethylene glycol causes birth defects in experimental animals. Tests
for carcinogenicity in experimental animals are negative.
SECTION 12 - ECOLOGICAL INFORMATION
This formulation has not been tested for environmental effects.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL:
Disposal of this product must comply with all applicable federal,
state and local regulations.
CONTAINER DISPOSAL:
Disposal of this container should comply with all applicable federal,
state and local regulations.
SECTION 14 - TRANSPORT INFORMATION
UN Number none
UN Pack Group N/A
UN Class Nonhaz
ICAO/IATA Class Nonhazardous
IMDG Class Nonhazardous
Shipping Name Nonhazardous
Packaging may not be approved for shipping by air. Please contact
Franklin International for further information.
SECTION 15 - REGULATORY INFORMATION
SARA TITLE III SECTION 313:
This product contains the following toxic chemicals subject to the
reporting requirements of Section 313 of the Emergency Planning and
Community Right to Know Act of 1986 and of 40 CFR 372:
Chemical Name CAS Number Percent
ethylene glycol 107-21-1 1.52
TSCA (Toxic Substances Control Act Inventory):
All components of this product are listed on the TSCA inventory except
as exempted.
PENNSYLVANIA:
Hazardous components required to be listed at 1% or more:
crystalline silica; quartz; 14808-60-7
kaolin clay; kaolin; 1332-58-7
ethylene glycol; 1,2-ethandiol; 107-21-1
Non-hazardous components required to be listed at 3% or more:
polyvinyl acetate emulison 24980-61-8; benzyl butyl phthalate
85-68-7;vinyl acetate/ethylene copolymer mixture
NEW JERSEY:
crystalline silica 14808-60-7; clay 1332-56-7; polyvinyl acetate
emulsion 24980-61-8; vinyl acetate/ethylene coploymer mixture; benzyl
butyl phthalate 85-68-7
SECTION 16 - OTHER INFORMATION
DISCLAIMER:
While the information and recommendations set forth herein are
believed to be accurate as of the data hereof, Franklin International
makes no warranty, express or implied, with respect thereto and
disclaims all liability from reliance thereon.